Journal article
A magnetic and Mössbauer study of the layered compound (NH4)Fe(PO4) · H2O
Abstract
(NH4)Fe(PO4) · H2O was prepared using hydrothermal methods and studied using bulk magnetic and Mössbauer spectroscopic techniques. The compound appears to be isostructural with (NH4)Co(PO4) · H2O and (NH4)Cd(PO4) · H2O. Orthorhombic cell constants (Å) a = 5.684(1), b = 8.803(1), and c = 4.818(5) were determined from powder data on highly oriented samples. The structure consists of FeO6 layers stacked normal to the b-axis separated by NH+4 ions. …
Authors
Greedan JE; Reubenbauer K; Birchall T; Ehlert M; Corbin DR; Subramanian MA
Journal
Journal of Solid State Chemistry, Vol. 77, No. 2, pp. 376–388
Publisher
Elsevier
Publication Date
December 1988
DOI
10.1016/0022-4596(88)90261-7
ISSN
0022-4596