Acyclic boron-containing π-ligand complexes: η2- and η3-coordination modes Academic Article uri icon

  •  
  • Overview
  •  
  • Research
  •  
  • Identity
  •  
  • Additional Document Info
  •  
  • View All
  •  

abstract

  • Cyclic boron-containing π-ligands such as boratabenzenes and borollides are well established, in particular as supporting ligands. By contrast, the chemistry of acyclic boron-containing π-ligands has remained relatively unexplored, presumably in part due to the higher reactivity of acyclic π-ligands relative to cyclic analogues. This perspective is focused on the synthesis, structures and reactivity of isolated transition metal complexes bearing η(n)-coordinated (n = 2 or 3) acyclic boron-containing ligands. Both monometallic and multimetallic compounds are included, and are discussed with an emphasis on metal-ligand and intraligand bonding and parallels with hydrocarbon π-ligand complexes.

publication date

  • January 28, 2012