Journal article
Rapid and efficient entry to vinyl silanes from aldehydes employing a novel metalation–Peterson sequence
Abstract
Bis(trimethylsilyl)chloromethane undergoes a rapid and selective metalation with s-BuLi, yielding the nucleophilic bis(trimethylsilyl)methyl anion and providing a straightforward general entry to vinyl silanes from aromatic, aliphatic and vinyl aldehydes.
Authors
McNulty J; Das P
Journal
Chemical Communications, Vol. 0, No. 10, pp. 1244–1245
Publisher
Royal Society of Chemistry (RSC)
Publication Date
2008
DOI
10.1039/b716897g
ISSN
1359-7345