Planar P6E6 (E = Se, S) macrocycles incorporating P2N2 scaffolds Academic Article uri icon

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abstract

  • Oxidation of alkali metal derivatives of the dianions [E((t)BuN)P(μ-N(t)Bu)(2)P(N(t)Bu)E](2-) (E = S, Se) with I(2) produces 15-membered macrocycles in which a planar P(6)E(6) motif is stabilised by perpendicular P(2)N(2) scaffolds.

authors

  • Nordheider, Andreas
  • Chivers, Tristram
  • Thirumoorthi, Ramalingam
  • Vargas-baca, Ignacio
  • Woollins, J Derek

publication date

  • 2012