Imido-pyridine Ti(iv) compounds: synthesis of unusual imido–amido heterobimetallic derivatives Journal Articles

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abstract

Controlled generation of novel bridging or terminal imido-pyridine complexes is achieved, including the unusual species [Li(THF)][Ti(η⁵-C₅Me₅)(NR)(NHR)₂]. Computational studies corroborate its charge-separated nature.

authors

Pedrosa, Sergio
Vidal, Fernando
Lee, Lucia Myongwon
Vargas-baca, Ignacio
Gómez-Sal, Pilar
Mosquera, Marta EG

publication date

June 28, 2015

has subject area

0302 Inorganic Chemistry (FoR)
0307 Theoretical and Computational Chemistry (FoR)
0399 Other Chemical Sciences (FoR)
Inorganic & Nuclear Chemistry (Science Metrix)

published in

Dalton Transactions Journal