Imido-pyridine Ti(iv) compounds: synthesis of unusual imido–amido heterobimetallic derivatives Academic Article uri icon

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abstract

  • Controlled generation of novel bridging or terminal imido-pyridine complexes is achieved, including the unusual species [Li(THF)][Ti(η5-C5Me5)(NR)(NHR)2]. Computational studies corroborate its charge-separated nature.

authors

  • Pedrosa, Sergio
  • Vidal, Fernando
  • Lee, Lucia Myongwon
  • Vargas-baca, Ignacio
  • Gómez-Sal, Pilar
  • Mosquera, Marta EG

publication date

  • June 28, 2015