Journal article
Asymmetric induction via co-ordination to Cr(CO) 3 ; nucleophilic attack on acyclic carbenium ions
Abstract
Temporary complexation of (S)-(–)-1-phenylethanol by the Cr(CO)3 moiety allows the use of carbenium ions to bring about asymmetric transformations with a high degree of retention of configuration, even in open-chain compounds.
Authors
Top S; Jaouen G; McGlinchey MJ
Journal
Chemical Communications, Vol. 0, No. 23, pp. 1110–1112
Publisher
Royal Society of Chemistry (RSC)
Publication Date
1980
DOI
10.1039/c39800001110
ISSN
1359-7345