Journal article
Inner Coordination Sphere Control of Metal−Metal Superexchange in Ruthenium Dimers
Abstract
The dinuclear Ru(III) complexes trans-[{(NH(3))(4)Ru(py)}(2)(&mgr;-L)][PF(6)](4), where py represents pyridine and L represents 1,4-dicyanamidobenzene dianion (dicyd(2)(-)) derivatives dicyd(2)(-) (1), Me(2)dicyd(2)(-) (2), Cl(2)dicyd(2)(-) (3), and Cl(4)dicyd(2)(-) (4), have been prepared and characterized by electronic absorption spectroscopy and cyclic voltammetry. A crystal structure of the complex trans-[{(NH(3))(4)Ru(py)}(2)(&mgr;-dicyd)][PF(6)](4…
Authors
Rezvani AR; Bensimon C; Cromp B; Reber C; Greedan JE; Kondratiev VV; Crutchley RJ
Journal
Inorganic Chemistry, Vol. 36, No. 15, pp. 3322–3329
Publisher
American Chemical Society (ACS)
Publication Date
July 1, 1997
DOI
10.1021/ic9700260
ISSN
0020-1669