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Polydimethylsiloxane-air partition ratios for...
Journal article

Polydimethylsiloxane-air partition ratios for semi-volatile organic compounds by GC-based measurement and COSMO-RS estimation: Rapid measurements and accurate modelling

Abstract

Polydimethylsiloxane (PDMS) shows promise for use as a passive air sampler (PAS) for semi-volatile organic compounds (SVOCs). To use PDMS as a PAS, knowledge of its chemical-specific partitioning behaviour and time to equilibrium is needed. Here we report on the effectiveness of two approaches for estimating the partitioning properties of polydimethylsiloxane (PDMS), values of PDMS-to-air partition ratios or coefficients (KPDMS-Air), and time …

Authors

Okeme JO; Parnis JM; Poole J; Diamond ML; Jantunen LM

Journal

Chemosphere, Vol. 156, , pp. 204–211

Publisher

Elsevier

Publication Date

August 2016

DOI

10.1016/j.chemosphere.2016.04.094

ISSN

0045-6535