Journal article
Long-range Coulomb forces and localized bonds
Abstract
The ionic model is shown to be applicable to all compounds in which the atoms carry a net charge and their electron density is spherically symmetric regardless of the covalent character of the bonding. By examining the electric field generated by an array of point charges placed at the positions of the ions in over 40 inorganic compounds, we show that the Coulomb field naturally partitions itself into localized regions (bonds) which are …
Authors
Preiser C; Lösel J; Brown ID; Kunz M; Skowron A
Journal
Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, Vol. 55, No. 5, pp. 698–711
Publisher
International Union of Crystallography (IUCr)
Publication Date
October 1, 1999
DOI
10.1107/s0108768199003961
ISSN
2052-5192