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Journal article

Synthesis and Properties of Carborane-Functionalized Aliphatic Polyester Dendrimers

Abstract

The incorporation of multiple p-carborane cages within an aliphatic polyester dendrimer was accomplished through the preparation of a bifunctional carborane synthon. A p-carborane derivative having an acid and a protected alcohol functionality was found to efficiently couple to peripheral hydroxyl groups of low-generation dendrimers under standard esterification conditions. Deprotection of carborane hydroxyl groups allowed for further …

Authors

Parrott MC; Marchington EB; Valliant JF; Adronov A

Journal

Journal of the American Chemical Society, Vol. 127, No. 34, pp. 12081–12089

Publisher

American Chemical Society (ACS)

Publication Date

August 1, 2005

DOI

10.1021/ja053730l

ISSN

0002-7863