Immobilization of tetrabromobisphenol A by pinecone-derived biochars at solid-liquid interface: Synchrotron-assisted analysis and role of inorganic fertilizer ions

The immobilization of tetrabromobisphenol A (TBBPA) by pinecone-derived biochars at solid-liquid interface was investigated in this study. The surface structures and functional groups of biochars produced at different temperatures were characterized through synchrotron-assisted FTIR analysis. The adsorption isotherms were well described by the Langmuir model. The adsorption capacity of TBBPA varied as pH and TBBPA initial concentration changed and the molecular form of TBBPA predominated in pH 5–7 played an important role. The influences of inorganic fertilizer ions ( NH 4 + , PO 4 3 - and NO 3 - ) on the immobilization of TBBPA by pinecone biochars were revealed through fractional-factorial assisted analysis. The results indicated the main effects include negative effects of PO 4 3 - , positive effects of NH 4 + and insignificant effects of NO 3 - ions in immobilization and there are interactions among these ions, pH and biochar properties. The results of this study can help understand migration patterns of TBBPA and analyze the immobilization on biochars in the presence of inorganic fertilizer ions. It will have important implications for risk assessment and site remediation regarding overall environmental performance.