Theory of ortho-para conversion in solid hydrogen at high densities

An expression is derived for the ortho-para conversion rate, as a function of density ρ, of solid ortho-H2 in its rotationally disordered state. For ρ greater than about 1.1 times the zero-pressure density ρ0, conversion is shown to result from a one-phonon process. This rate is proportional to (ρρ0)103-2γ, where γ is the Grüneisen constant for solid H2, times a phonon spectral function which depends on the density as a parameter. Using the …