Journal article
Atom transfer radical polymerization of alkyl methacrylates using T‐triazine as ligand
Abstract
A new multidentate amine ligand, 1,3,5‐tris[(3‐dimethylamino)propyl]‐hexahydro‐1,3,5‐triazine (T‐triazine) was developed for the atom transfer radical polymerization of methacrylates (dimethylaminoethyl methacrylate (DMAEMA) and methyl methacrylate (MMA)). It was found that with T‐triazine as ligand, CuBr mediated a living polymerization of DMAEMA and MMA, producing polymers with controlled molecular weight and narrow polydispersity. The DMAEMA …
Authors
Shen Y; Zhu S; Zeng F; Pelton RH
Journal
Macromolecular Chemistry and Physics, Vol. 201, No. 11, pp. 1169–1175
Publisher
Wiley
Publication Date
July 1, 2000
DOI
10.1002/1521-3935(20000701)201:11<1169::aid-macp1169>3.0.co;2-g
ISSN
1022-1352