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A double quantum 129Xe NMR experiment for probing...
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A double quantum 129Xe NMR experiment for probing xenon in multiply-occupied cavities of solid-state inclusion compounds

Abstract

A method is presented for detecting multiple xenon atoms in cavities of solid-state inclusion compounds using (129)Xe double quantum NMR spectroscopy. Double quantum filtered (129)Xe NMR spectra, performed on the xenon clathrate of Dianin's compound were obtained under high-resolution Magic-Angle Spinning (MAS) conditions, by recoupling the weak (129)Xe-(129)Xe dipole-dipole couplings that exist between xenon atoms in close spatial proximity. …

Authors

Brouwer DH; Alavi S; Ripmeester JA

Volume

9

Pagination

pp. 1093-1098

Publisher

Royal Society of Chemistry (RSC)

Publication Date

2007

DOI

10.1039/b616434j

Conference proceedings

Physical Chemistry Chemical Physics

Issue

9

ISSN

1463-9076