ChemInform Abstract: Development of a Robust Reagent for the Two‐Carbon Homologation of Aldehydes to (E)‐α,β‐Unsaturated Aldehydes in Water. Journal Articles uri icon

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abstract

  • AbstractThe new pinacolacetalphosphonium salt (V) smoothly reacts with aldehydes in aqueous medium to give homologated acetals which hydrolyze to corresponding two‐carbon homologated unsaturated aldehydes with excellent (E)‐selectivity.

publication date

  • March 18, 2014