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Breaking Parallel Orientation of Rods via a...
Journal article

Breaking Parallel Orientation of Rods via a Dendritic Architecture toward Diverse Supramolecular Structures

Abstract

Self-assembled nanostructures of rod-like molecules are commonly limited to nematic or layered smectic structures dominated by the parallel arrangement of the rod-like components. Distinct self-assembly behavior of four categories of dendritic rods constructed by placing a tri(hydroxy) group at the apex of dendritic oligo-fluorenes is observed. Designed hydrogen bonding and dendritic architecture break the parallel arrangement of the rods, …

Authors

Zhang R; Feng X; Zhang R; Shan W; Su Z; Mao J; Wesdemiotis C; Huang J; Yan X; Liu T

Journal

Angewandte Chemie International Edition, Vol. 58, No. 34, pp. 11879–11885

Publisher

Wiley

Publication Date

August 19, 2019

DOI

10.1002/anie.201904749

ISSN

1433-7851