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Operando Mapping of Li Concentration Profiles and...
Journal article

Operando Mapping of Li Concentration Profiles and Phase Transformations in Graphite Electrodes by Magnetic Resonance Imaging and Nuclear Magnetic Resonance Spectroscopy

Abstract

An innovative combined magnetic resonance imaging and nuclear magnetic resonance methodology, which enables the visualization and spatially resolved quantification of the lithiation/delithiation process in porous Li-ion battery electrodes in real time, is reported. We demonstrate that polarization of the thick graphite electrode correlates with the appearance of energy barriers during the graphite phase transformations and the resulting …

Authors

Krachkovskiy SA; Foster JM; Bazak JD; Balcom BJ; Goward GR

Journal

The Journal of Physical Chemistry C, Vol. 122, No. 38, pp. 21784–21791

Publisher

American Chemical Society (ACS)

Publication Date

September 27, 2018

DOI

10.1021/acs.jpcc.8b06563

ISSN

1932-7447