Journal article
NMR spectroscopic study of xenon fluorides in the gas phase and of XeF2 in the solid state
Abstract
The xenon fluorides, XeF2, XeF4, and XeF6, were characterized by gas-phase 129Xe and 19F NMR spectroscopy, providing the first gas-phase NMR spectroscopic data for the xenon fluorides. Xenon difluoride was also characterized in the solid state by static and magic angle spinning (MAS) 129Xe and 19F NMR spectroscopy, providing experimental values for the 129Xe (4260±10ppm) and 19F (125±5ppm) shielding anisotropies in XeF2. A method for …
Authors
Gerken M; Hazendonk P; Nieboer J; Schrobilgen GJ
Journal
Journal of Fluorine Chemistry, Vol. 125, No. 7, pp. 1163–1168
Publisher
Elsevier
Publication Date
July 2004
DOI
10.1016/j.jfluchem.2004.04.001
ISSN
0022-1139