Journal article
Syntheses and Structures of TcOF5 and the Tc2O2F9 + Cation and Formation of the TcOF4 + Cation in Solution †
Abstract
The last member of the series of technetium(VII) oxide fluorides, TcOF5, has been prepared by oxidative fluorination of TcO2F3 with KrF2 in anhydrous HF. The pseudooctahedral (C 4 v ) structure of TcOF5 has been determined by 19F and 99Tc NMR, Raman, and infrared spectroscopies and by single-crystal X-ray diffraction. TcOF5 crystallizes in the orthorhombic crystal system, space group Pna21, with a = 9.235(3) Å, b = 4.939(2) Å, c = 8.502(3) Å, V …
Authors
LeBlond N; Mercier HPA; Dixon DA; Schrobilgen GJ
Journal
Inorganic Chemistry, Vol. 39, No. 20, pp. 4494–4509
Publisher
American Chemical Society (ACS)
Publication Date
October 1, 2000
DOI
10.1021/ic991397e
ISSN
0020-1669