Journal article
A Rare Example of a Krypton Difluoride Coordination Compound: [BrOF2][AsF6]·2KrF2
Abstract
The synthesis of [BrOF(2)][AsF(6)] x 2 KrF(2), its structural characterization, and bonding are described in this study. Although several KrF(2) adducts with transition metal centers have been previously reported, none have been crystallographically characterized. The solid-state Raman spectrum of [BrOF(2)][AsF(6)] x 2 KrF(2) has been assigned with the aid of quantum-chemical calculations. The low-temperature (-173 degrees C) X-ray crystal …
Authors
Brock DS; de Pury JJC; Mercier HPA; Schrobilgen GJ; Silvi B
Journal
Journal of the American Chemical Society, Vol. 132, No. 10, pp. 3533–3542
Publisher
American Chemical Society (ACS)
Publication Date
March 17, 2010
DOI
10.1021/ja9098559
ISSN
0002-7863