Journal article
Fluoride Ion Donor Properties of cis-OsO2F4: Synthesis, Raman Spectroscopic Study, and X-ray Crystal Structure of [OsO2F3][Sb2F11]
Abstract
The salt, [OsO(2)F(3)][Sb(2)F(11)], has been synthesized by dissolution of cis-OsO(2)F(4) in liquid SbF(5), followed by removal of excess SbF(5) at 0 degrees C to yield orange, crystalline [OsO(2)F(3)][Sb(2)F(11)]. The X-ray crystal structure (-173 degrees C) consists of an OsO(2)F(3)(+) cation fluorine bridged to an Sb(2)F(11)(-) anion. The light atoms of OsO(2)F(3)(+) and the bridging fluorine atom form a distorted octahedron around osmium in …
Authors
Hughes MJ; Mercier HPA; Schrobilgen GJ
Journal
Inorganic Chemistry, Vol. 49, No. 1, pp. 271–284
Publisher
American Chemical Society (ACS)
Publication Date
January 4, 2010
DOI
10.1021/ic901999e
ISSN
0020-1669