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Role of Stress in Thin Film Alloy Thermodynamics:...
Journal article

Role of Stress in Thin Film Alloy Thermodynamics: Competition between Alloying and Dislocation Formation

Abstract

Using scanning tunneling microscopy (STM) and first-principles local-spin-density-approximation calculations to study submonolayer films of Co (1-c)Ag (c)/Ru(0001) alloys, we have discovered a novel phase-separation mechanism. When the Ag concentration c exceeds 0.4, the surface phase separates between a dislocated, pure Ag phase and a pseudomorphically strained Co(0.6)Ag (0.4) surface alloy. We attribute the phase separation to the competition …

Authors

Thayer GE; Ozolins V; Schmid AK; Bartelt NC; Asta M; Hoyt JJ; Chiang S; Hwang RQ

Journal

Physical Review Letters, Vol. 86, No. 4, pp. 660–663

Publisher

American Physical Society (APS)

Publication Date

January 22, 2001

DOI

10.1103/physrevlett.86.660

ISSN

0031-9007