Model‐Based Production of Polymer Chains Having Precisely Designed End‐to‐End Gradient Copolymer Composition and Chain Topology Distributions in Controlled Radical Polymerization, A Review

Polymer chain microstructures, such as copolymer composition distribution (CCD) and topology, play an important role in determining materials properties of the polymer products. The design and control of polymer chain microstructures represents an important task in macromolecular reaction engineering. Semi‐batch copolymerization with the model‐based design of comonomer feeding policies provides a powerful approach enabling precision production …