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The Nature of Crosslinking in N‐Vinylformamide...
Journal article

The Nature of Crosslinking in N‐Vinylformamide Free‐Radical Polymerization

Abstract

N‐Vinylformamide (NVF) free‐radical polymerization was found to form polymer gels at high conversions both in bulk and in solution. The polymerization was conducted at different temperatures, monomer and initiator concentrations to show the gelation conditions. Gel fractions and gel swelling ratios were also measured after separating the gel from the polymer samples. In order to confirm the crosslinking unit, a series of hydrolysis experiments …

Authors

Gu L; Zhu S; Hrymak AN; Pelton RH

Journal

Macromolecular Rapid Communications, Vol. 22, No. 3, pp. 212–214

Publisher

Wiley

Publication Date

February 2001

DOI

10.1002/1521-3927(200102)22:3<212::aid-marc212>3.0.co;2-b

ISSN

1022-1336