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Inept-29Si NMR study of a TiCl4-mediated reaction...

Journal article

Inept-29Si NMR study of a TiCl4-mediated reaction of an enol silyl ether

Abstract

Condensation of 1,3-bis(trimethylsiloxy)-1-methoxybutadiene (1) and 2-phenyl-2,2-dimethoxyethanal (2) under TiCl4 condition gave the γ-hydroxycyclopentenone product 3. The reaction was followed by INEPT29Si NMR. Implication to the mechanism of the reaction was discussed.

Authors

Chan TH; Brook MA

Journal

Tetrahedron Letters, Vol. 26, No. 25, pp. 2943–2946

Publisher

Elsevier

Publication Date

January 1, 1985

DOI

10.1016/s0040-4039(00)98587-3

ISSN

0040-4039

Associated Experts

Michael Adrian Brook

Professor Emeritus, Faculty of Science

Labels

Fields of Research (FoR)

3402 Inorganic Chemistry 3405 Organic chemistry 34 Chemical Sciences 3101 Biochemistry and cell biology 3404 Medicinal and biomolecular chemistry

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