Journal article
Inept-29Si NMR study of a TiCl4-mediated reaction of an enol silyl ether
Abstract
Condensation of 1,3-bis(trimethylsiloxy)-1-methoxybutadiene (1) and 2-phenyl-2,2-dimethoxyethanal (2) under TiCl4 condition gave the γ-hydroxycyclopentenone product 3. The reaction was followed by INEPT29Si NMR. Implication to the mechanism of the reaction was discussed.
Authors
Chan TH; Brook MA
Journal
Tetrahedron Letters, Vol. 26, No. 25, pp. 2943–2946
Publisher
Elsevier
Publication Date
January 1985
DOI
10.1016/s0040-4039(00)98587-3
ISSN
0040-4039