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Silicone dendrons and dendrimers from orthogonal...
Journal article

Silicone dendrons and dendrimers from orthogonal SiH coupling reactions

Abstract

Iterative assembly of highly branched silicone dendrons and dendrimers, alternatively using Piers–Rubinsztajn and Pt-catalyzed hydrosilylation reactions, was achieved in high yield to give materials of up to 13 770 molecular weight by combining divergent and convergent approaches.

Authors

Grande JB; Urlich T; Dickie T; Brook MA

Journal

Polymer Chemistry, Vol. 5, No. 23, pp. 6728–6739

Publisher

Royal Society of Chemistry (RSC)

Publication Date

2014

DOI

10.1039/c4py00680a

ISSN

1759-9954