Core Excitation Spectroscopy of Phenyl- and Methyl-Substituted Silanol, Disiloxane, and Disilane Compounds: Evidence for π-Delocalization across the Si−Cphenyl Bond

The Si 1s and 2p solid state photoabsorption (total electron yield) spectra of triphenylsilanol, hexaphenyldisiloxane, and hexaphenyldisilane and the Si 1s spectra (total ion yield) of gaseous trimethylsilanol, hexamethyldisiloxane, hexamethyldisilane, and trimethylmethoxysilane have been recorded using synchrotron radiation. These spectra are compared to inner shell electron energy loss spectra of gaseous triphenylsilanol, hexaphenyldisilane, …