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Everything is a Mean Field: Exact Description of...
Journal article

Everything is a Mean Field: Exact Description of Electronic Structure with Antisymmetric Products of Quasiparticles

Abstract

We show that electronic wavefunctions can be described, exactly, as the projection of a number-symmetry-broken antisymmetric product of geminals onto the appropriate N-electron Hilbert space. The same argument works for other composite bosons (tetrads, hexads, etc.). Inasmuch as every wavefunction can be rewritten as an antisymmetric product of quasiparticles, “everything is a mean field”.

Authors

Ayers PW; González MM

Journal

Theoretical Chemistry Accounts, Vol. 144, No. 12,

Publisher

Springer Nature

Publication Date

December 1, 2025

DOI

10.1007/s00214-025-03255-9

ISSN

1432-881X

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