Water-Induced Dual Switching of Magnetic Properties and Proton Conduction in a Hydrogen-Bonded Manganese(II)-Organosulfonate Framework

Abstract

Dynamic modulation of magnetic and electrical properties through single-crystal-to-single-crystal (SCSC) transformations has always been difficult. Herein, we report the synthesis, structures, magnetic and proton conduction properties of a dynamic manganese(II) hydrogen-bonded organic framework (MnHOF), formulated as {[Mn(bpy)(H2O)4]·2NPS·H2O} n (denoted as 1·H 2 O, NPS = naphthalenesulfonate, bpy = 4,4′-bipyridine). This framework is …