Decorated phases in triblock copolymers: zeroth- and first-order analysis
Abstract
We study a two-dimensional inhibitory ternary system characterized by a free
energy functional which combines an interface short-range interaction energy
promoting micro-domain growth with a Coulomb-type long-range interaction energy
which prevents micro-domains from unlimited spreading. Here we consider a
scenario in which two species are dominant and one species is vanishingly
small. In this scenario two energy levels are distinguished: the zeroth-order
energy encodes information on the optimal arrangement of the dominant
constituents, while the first-order energy gives the shape of the vanishing
constituent. This first-order energy also shows that, for any optimal
configuration, the vanishing phase must lie on the boundary between the two
dominant constituents and form lens clusters also known as vesica piscis.