Journal article
Manganese(II) Alkyl/π-Allyl Complexes Resistant to Ligand Redistribution
Abstract
The reaction of [Li(THF)4][(Mn{C(SiMe3)3})3(μ-Cl)4(THF)] (1) with K(allylTMS2) (allylTMS2 = 1,3-C3H3(SiMe3)2) afforded [(η3-allylTMS2)Mn{C(SiMe3)3}{ClLi(THF)3}] (2). Attempted sublimation of 2 yielded [(η3-allylTMS2)Mn{C(SiMe3)3}(THF)] (3), indicating that 2 extrudes LiCl at elevated temperatures. Additionally, LiCl in 2 was displaced by reaction with PMe3, quinuclidine, and dmap (dmap = 4-(dimethylamino)pyridine), providing …
Authors
Chadha P; Emslie DJH; Jenkins HA
Journal
Organometallics, Vol. 33, No. 6, pp. 1467–1474
Publisher
American Chemical Society (ACS)
Publication Date
March 24, 2014
DOI
10.1021/om500101m
ISSN
0276-7333