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The Challenge of Paramagnetism in Two-Dimensional...
Journal article

The Challenge of Paramagnetism in Two-Dimensional 6,7Li Exchange NMR

Abstract

Abstract.6,7Li fast magic-angle spinning solid-state nuclear magnetic resonance (NMR) spectroscopy is used to study LiMn2O4 and Li3V2(PO4)3. The presence of paramagnetic transition metal centers in these materials has a profound effect on the resulting NMR spectra. Lithium ion mobility has been studied by two-dimensional (2-D) exchange spectroscopy (EXSY) in Li3V2(PO4)3 but an absence of lithium ion exchange was observed for LiMn2O4. Several …

Authors

Cahill LS; Chapman RP; Kirby CW; Goward GR

Journal

Applied Magnetic Resonance, Vol. 32, No. 4, pp. 565–581

Publisher

Springer Nature

Publication Date

December 2007

DOI

10.1007/s00723-007-0046-8

ISSN

0937-9347