Journal article
The Effect of Steric Hindrance on the Association of Telluradiazoles through Te−N Secondary Bonding Interactions
Abstract
DFT calculations were used to compare the magnitude of steric repulsion to the strength of secondary bonding interactions (SBIs) in the (Te−N)2 supramolecular synthon to explain or predict the supramolecular structures assembled by two derivatives of the 1,2,5-telluradiazole ring: benzo-2,1,3-telluradiazole (4c) and 3,6-dibromobenzo-2,1,3-telluradiazole (5). The crystallographically determined structures were consistent with the computational …
Authors
Cozzolino AF; Britten JF; Vargas-Baca I
Journal
Crystal Growth & Design, Vol. 6, No. 1, pp. 181–186
Publisher
American Chemical Society (ACS)
Publication Date
January 1, 2006
DOI
10.1021/cg050260y
ISSN
1528-7483