Self-assembly of grafted Y-shaped ABC triblock copolymers in solutions

Self-assembled morphologies of grafted Y-shaped ABC triblock copolymers are investigated using a simulated annealing method. The block copolymers are composed of two incompatible arms (A and B) and a short stem (C), with the C-stems grafted onto a flat surface. A rich array of novel morphologies is discovered. The formation of these morphologies is controlled by polymer grafting density, the incompatibility between the A-B-blocks, as well as …