Journal article
7Li NMR and Two-Dimensional Exchange Study of Lithium Dynamics in Monoclinic Li3V2(PO4)3
Abstract
High-resolution solid-state (7)Li NMR was used to characterize the structure and dynamics of lithium ion transport in monoclinic Li(3)V(2)(PO(4))(3). Under fast magic-angle spinning (MAS) conditions (25 kHz), three resonances are clearly resolved and assigned to the three unique crystallographic sites. This assignment is based on the Fermi-contact delocalization interaction between the unpaired d-electrons at the vanadium centers and the …
Authors
Cahill LS; Chapman RP; Britten JF; Goward GR
Journal
The Journal of Physical Chemistry B, Vol. 110, No. 14, pp. 7171–7177
Publisher
American Chemical Society (ACS)
Publication Date
April 1, 2006
DOI
10.1021/jp057015+
ISSN
1520-6106