Journal article
Structure and formation of the first (–O–Te–N–) 4 ring
Abstract
A twelve-membered macrocycle featuring the periodic -O-Te-N- sequence was obtained from the reaction of a β-(N,N-dimethylcarbamoyl-chalcogeno)-alkenyl ketone with hydroxylamine-O-sulfonic acid. A computational study suggests that the ring is assembled by spontaneous catenation of an intermediate isotellurazole-N-oxide.
Authors
Kübel J; Elder PJW; Jenkins HA; Vargas-Baca I
Journal
Dalton Transactions, Vol. 39, No. 46, pp. 11126–11128
Publisher
Royal Society of Chemistry (RSC)
Publication Date
2010
DOI
10.1039/c0dt01102a
ISSN
1477-9226