Uranium( iv ) alkyl cations: synthesis, structures, comparison with thorium( iv ) analogues, and the influence of arene-coordination on thermal stability and ethylene polymerization activity

Reaction of [(XA₂)U(CH₂SiMe₃)₂] (1; XA₂ = 4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethylxanthene) with 1 equivalent of [Ph₃C][B(C₆F₅)₄] in arene solvents afforded the arene-coordinated uranium alkyl cations, [(XA₂)U(CH₂SiMe₃)(η ⁿ -arene)][B(C₆F₅)₄] {arene = benzene (2), toluene (3), bromobenzene (4) and fluorobenzene (5)}. Compounds 2, 3, and 5 were crystallographically characterized, and in all cases the arene is π-coordinated. …