Journal article
Stopping a chromium carousel: X -ray crystallographic and variable-temperature 13 C n. m. r. studies on dicarbonyl(hexaethylbenzene)-thiocarbonylchromium(0) and related complexes
Abstract
The low temperature 13C n.m.r. spectrum of (C6Et6)Cr(CO)2CS shows the molecule to have Cs symmetry as it does in the solid state; this result provides the first clear evidence of cessation of tripodal rotation in a neutral half-sandwich compound of Cr.
Authors
McGlinchey MJ; Fletcher JL; Sayer BG; Bougeard P; Faggiani R; Lock CJL; Bain AD; Rodger C; Kündig EP; Astruc D
Journal
Chemical Communications, Vol. 0, No. 11, pp. 634–636
Publisher
Royal Society of Chemistry (RSC)
Publication Date
1983
DOI
10.1039/c39830000634
ISSN
1359-7345