A determination of the oxidation states and internal stresses in Ba2YCu3Ox, x = 6 – 7 using bond valences

A bond valence analysis of the title compound indicates that Cu1+ is found only on the Cu1 site but Cu3+ is found on both sites with a 25% occupancy on Cu2 and a 50% occupancy on Cu1 for x = 7. The analysis also predicts how the electron holes would be distributed over the four crystallographically distinct O atoms if they reside on the O rather than the Cu atoms. Modeling the two end members using Kirchoff-like network equations and a …