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On the valences of bonds in the oxycomplexes of...
Journal article

On the valences of bonds in the oxycomplexes of Sn2+

Abstract

The differences between Wang and Liebau's [Wang & Liebau (2007). Acta Cryst. B63, 216-228] stoichiometric valence (atomic valence) and structural valence (bond-valence sum) observed in Sn(2+) and other lone-pair cation oxycomplexes arises from their use of the Brese & O'Keeffe bond-valence parameters which are based on the assumption that the bond-valence parameter b = 0.37 A applies to all bond types. According to the theory of the …

Authors

Brown ID

Journal

Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, Vol. 65, No. 6, pp. 684–693

Publisher

International Union of Crystallography (IUCr)

Publication Date

December 1, 2009

DOI

10.1107/s0108768109034417

ISSN

2052-5192