Journal article
Theory, Substantiation, and Properties of Novel Reversible Electrocatalysts for Oxygen Electrode Reactions
Abstract
Hypo-d–(f)-oxides of transition elements (d ≤ 5) usually feature decisive and highly pronounced effects of spontaneous adsorptive dissociation of water molecules, as the main and initial thermodynamic precondition state for the reversible latent storage and spillover properties of primary oxides (Pt–OH, Au–OH), otherwise indispensable ingredients in electrocatalysis for the oxygen electrode reactions. The higher the altervalent number (or …
Authors
Jaksic JM; Nan F; Papakonstantinou GD; Botton GA; Jaksic MM
Journal
The Journal of Physical Chemistry C, Vol. 119, No. 21, pp. 11267–11285
Publisher
American Chemical Society (ACS)
Publication Date
May 28, 2015
DOI
10.1021/jp510234f
ISSN
1932-7447