Journal article
Intercluster exchanges leading to hydride-centered bimetallic clusters: a multi-NMR, X-ray crystallographic, and DFT study
Abstract
Encouraged by the successful syntheses of alloy nanoclusters (or nanoparticles) via intercluster (or interparticle) reactions, herein we apply this methodology to prepare a series of bimetallic hydride clusters. Mixing of two clusters, [Ag7(H){E2P(OiPr)2}6] (E = S, 1; Se, 3) and [Cu7(H){E2P(OiPr)2}6] (E = S, 2; Se, 4), yields two series of hydride-centered bimetallic clusters, [CuxAg7-x(H){E2P(OiPr)2}6] (x = 0-7; E = S, 5; Se, 6). Their …
Authors
Zhong Y-J; Liao J-H; Chiu T-H; Wu Y-Y; Kahlal S; McGlinchey MJ; Saillard J-Y; Liu CW
Journal
Dalton Transactions, Vol. 50, No. 13, pp. 4727–4734
Publisher
Royal Society of Chemistry (RSC)
Publication Date
April 7, 2021
DOI
10.1039/d1dt00072a
ISSN
1477-9226