Journal article
Mössbauer spectroscopy of KrF2 and KrF2· MF5 (M=As, Sb)
Abstract
Mössbauer spectra of KrF2 and the recently synthesized compounds α- and β- [KrF]+[AsF6 ]- and [KrF]+[SbF6 ]- have been measured using the 9.4 keV transition of 83Kr produced in the decay of an 83RbF source. The results for the values of quadrupole coupling strengths and the isomer shifts indicate that the Kr-F bonding in all compounds studied is very similar. A slight increase of the quadrupole coupling in going from KrF2 to F-Kr-F-MF5 can be …
Authors
Holloway JH; Schrobilgen GJ; Bukshpan S; Hilbrants W; De Waard H
Journal
Journal of Chemical Physics, Vol. 66, No. 6, pp. 2627–2630
Publication Date
January 1, 1976
DOI
10.1063/1.434262
ISSN
0021-9606