Large Kondo effect in assemblies of Au nanoparticles linked with alkanedithiol electron bridges

Using a prototypical nanoparticle-molecule assembly, namely alkanedithiol-linked gold nanoparticle films, we observe hallmark signatures of the Kondo effect in conductance vs. voltage as well as temperature measurements. Its contribution to temperature dependence of conductance is much larger than those from all other temperature-dependant effects up to 300 K by >20-fold - much larger than previous reports of the Kondo effect using other …