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Synthetic hydrogels formed by thiol–ene...
Journal article

Synthetic hydrogels formed by thiol–ene crosslinking of vinyl sulfone-functional poly(methyl vinyl ether- alt -maleic acid) with α,ω-dithio-polyethyleneglycol

Abstract

Polymer hydrogels formed by rapid thiol-ene coupling of macromolecular gel formers can offer access to versatile new matrices. This paper describes the efficient synthesis of cysteamine vinyl sulfone (CVS) trifluoroacetate, and its incorporation into poly(methyl vinyl ether-alt-maleic anhydride) (PMMAn) to form a series of CVS-functionalized poly(methyl vinyl ether-alt-maleic acid) polymers (PMM-CVSx) containing 10 to 30 mol% pendant vinyl …

Authors

Stewart SA; Coulson MB; Zhou C; Burke NAD; Stöver HDH

Journal

Soft Matter, Vol. 14, No. 41, pp. 8317–8324

Publisher

Royal Society of Chemistry (RSC)

Publication Date

November 7, 2018

DOI

10.1039/c8sm01066h

ISSN

1744-683X