Journal article
Definitive characterization of some C5H5N·+ and C6H7N·+ radical cations by associative ion–molecule reactions
Abstract
Isomeric C5H5N·+ and C6H7N·+ radical cations were allowed to interact with various neutral reagents in the quadrupole collision chamber of a six sector magnetic deflection type tandem mass spectrometer. Using CH3SSCH3, CH3OH, or H2O, iso-C3H7I, and tert-C4H9NC as substrates, specific associative ion–molecule reactions occur whose products were analyzed in a subsequent high energy collision induced dissociation experiment. Differentiation …
Authors
Gerbaux P; Barbieux-Flammang M; Terlouw JK; Flammang R
Journal
International Journal of Mass Spectrometry, Vol. 206, No. 1-2, pp. 91–103
Publisher
Elsevier
Publication Date
February 2001
DOI
10.1016/s1387-3806(00)00393-6
ISSN
1387-3806