Journal article
Remarkable rearrangement–dissociation processes of gaseous protonated methyl formate involving ion–dipole complexes
Abstract
Collision induced decarbonylation of 13C, 18O-labelled protonated methyl formate, HC(OH)O*C*H3, involves the loss of both CO (40%) and CO*; the intermediacy of proton-bound dimers and ion–dipole complexes is invoked to explain the mechanisms.
Authors
van Baar B; Halim H; Terlouw JK; Schwarz H
Journal
Chemical Communications, Vol. 0, No. 9, pp. 728–730
Publisher
Royal Society of Chemistry (RSC)
Publication Date
1986
DOI
10.1039/c39860000728
ISSN
1359-7345