Gas‐phase chemistry of the methyl carbamate radical cation, H2NCOOCH. II—A test case for ion structure assignment

Abstract The unimolecular chemistry of the methyl carbamate radical cation, H 2 NCOOCH , 1, has been further investigated by a combination of mass spectrometry‐based experiments (metastable ion (MI), collisional activation (CA), collision‐induced dissociative ionization (CIDI), neutralization‐reionization (NR) Spectrometry and 2 H labelling) and ab initio molecular orbital calculations, executed at the MP3/6–31G*//4–31G level of theory and …