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Effect of aluminoxane on semi-batch polymerization...
Journal article

Effect of aluminoxane on semi-batch polymerization of ethylene using zirconocene dichloride

Abstract

Several types of commercial and developmental aluminoxanes were studied in the semi-batch polymerization of ethylene using bis(cyclopentadienyl) zirconium dichloride (Cp2ZrCl2). High temperature gel permeation chromatography (GPC) measurements of polyethylene (PE) formed using various types of aluminoxanes approximated Flory's most probable distribution from a single site-type with PE Mw/Mns approaching 2.0 for polymerization temperatures …

Authors

Charpentier PA; Zhu S; Hamielec AE; Brook MA

Journal

Polymer, Vol. 39, No. 25, pp. 6501–6511

Publisher

Elsevier

Publication Date

12 1998

DOI

10.1016/s0032-3861(98)00064-0

ISSN

0032-3861