Bubble nucleation in nonpressurized polymer foaming systems

The mechanism of bubble nucleation in the foaming process under atmospheric pressure is investigated in the present study. The experimental observations using a plastic‐foaming visualization setup revealed two stages of nucleation, primary nucleation in interstitial regions and secondary nucleation in the polymer melt, which followed the sintering and densification of the polymer matrix. Statistical analysis of the evolving cellular structure during the nucleation stage was used to study the significance of rheology on the behavior of polymer materials during the nucleation. The role of viscosity on the nucleation rate was also investigated theoretically by using a modified form of the classical nucleation theory and it was verified with the experimentally observed data. POLYM. ENG. SCI., 54:1201–1210, 2014. © 2013 Society of Plastics Engineers